1. Darth Vader (James Earl Jones) “Star Wars”:

Being a decent Jedi Knight himself but later on turning to the dark side, Darth Vader is number one on our list for being the most villainy of villains. Whether it is his costume, the voice that will give you chills, or the mask that doesn’t allow you to see who exactly is behind all that evil, Darth Vader is everything evil and the actor did one hell of a job keeping up the expectations too.